Silica gel is a kind of highly active adsorption material.
It is usualIy formulated by sodium silicate and sulphuric acid reaction and through
a series of after treatment processes such as aging, pickling, etc. Silica gel is
amorphous substance. Its chemical molecular formula is SiO2.nH2O. It is insoluble
in water and any other solvent. It is nontoxic, non-odor and chemically stable. Except for
alkali and hydrofluoric acid, it does not react with any other substance. Owing to
their different manufacturing methods, the various types of silica gel are formulated
with different pore structures. Because of its unique chemical composition and physical
structure, silica gel possesses a number of characteristics with which other similar
materials are incomparable, such as high adsorption feature, stable thermal performance,
stable physical property and relatively high mechanical strength, etc.
According to the different pore diameters of silica gels, they are categorized into
large pore silica gel. Owing to their different pore structures, their adsorptive humidity,
macro-pored silica gel has a relatively high adsorption capacity. Whereas, under the
circumstance where there is a low relative humidity, fine-pored silica gel has a higher
adsorption capacity than macro-pored silica gel. The pore structure of silica gel Type B
lies between macro-pored and fine-pored silica gel, so its adsorption amount is also between
those of macro-pored and fine-pored silica gel. Large pored silica gel is usually used as
catalyst carrier, matting agent and toothpaste abrasive, etc. Therefore, the appropriate type
is to be selected according to your specific field of application.
Safety Performance
The main component of silica gel is silica, which is chemically stable and
flame-resisting. Silica gel is a kind of non-crystalline silica. The dust content inside
the workshop should be controlled to be no more than 10mg/m3. The workshop shall be
well-ventilated. Operators should wear mouth-muffles when processing.
The strong adsorption capability of silica gel may cause drying effects on human skins.
Therefore,operators should be instructed to wear working clothes when processing. If silica gel
accidentally comes into one's eyes, be sure to wash them using a large amount of water and seek
for medical care as soon as possible.
Containing small amount of cobalt chloride and being toxic, blue and orange silica gel should be kept
from contacting the foods and inhaling into one's mouth. Seek for medical care as soon as
possible once there is a poisoning accident.
Colloidal silica/silica sol's main composition is silicon dioxide and water, it is also non-toxic.But its main application is not absorption.
Reclamation
Since silica gel adsorbs steams and other organic substances from the media,
its adsorption capability declines. After being reclaimed, it can be used again.
The reclaim of silica gel after steam adsorption
After adsorbing moistures, the moistures contained in silica gel
can be removed by heating de-adsorption. There are many methods for heating,
for example, by electrically heated stove, remaining heat in the flue and hot air drying, etc.
For heating de-adsprption, The temperature should be controlled to be within the
range of 120-180℃.For blue gel indicator, chromotropic silica gel and blue silica gel DL,
the temperature should be controlled to be within 100-120℃.
When reclaiming industrial silica gels, make sure the highest temperatures are within the following limits:
Macro-pored silica gel no more than 600℃
Fine-pored silica gel no more than 200℃
Blue silica gel and orange silica gel (or chromotropic silica gel) no more than 120℃
Silica alumina gel no more than 350℃
The reclaimed silica gel can be put into use again as long as
its moisture content is controlled to be less than 2%.
The reclamation after organic impurities adsorption
1. Roasting
Put macro-pored silica gel into a roaster and gradually rise its temperature
to 500-6℃.After about 6-8 hours,the gel grains become white or yellowish-brown.
For fine-pored silica gel, the roasting temperature shall be not more than 200℃.
2. Bleaching
Put silica gel into saturated steam to adsorb until it is fully saturated,
then drop it into hot water to soak and bleach. Detergent can also be used to remove
the waste oil and other organic impurities.After washing it in clean water,
dry it to remove the moistures.
3. Solvent Rinsing
Depending on the organic substances adsorbed by silica gel, select the appropriate
solvent to dissolve the organic substances adsorbed inside silica gel, then heat
up silica gel to get rid of the solvent.
Points for Attention in Silica Gel Reclamation
1. Gradually rise up the temperature in drying reclaim to prevent the gel
grains from exploding and thereby from reducing the recovery ratio as a result
of severe drying.
2. In roasting reclaim, excessively high temperature may cause changes to the pore
structure of silica gel, thereby substantially reducing its adsorption effect and affecting
its usefulness.For blue gel indicator or discoloring silica gel, the temperature for deadsorption
reclaim shall be not more than 120℃, otherwise, its developing agent will be gradually
oxidized and therefore lose its devdloping effect.
3. The reclaimed silica gel shall usually be sifted out to get rid of the fine grains,
thus making the grains well-distributed and uniform.
Storage and Packing
Silica gel is strong in moisture absorption, therefore, it should be stored in dry places.
Shelf racks should be put between the container and the floor. The containers are steel drums,
paper bags, cardboard boxes, plastic bottles, polyethylene plastic compound bags and flexible
container bags, etc. Please refer to the categorized product descriptions for detailed packing specifications.
All silica gel products should be kept from rain、moisture、sun.
The colloidal silica/silica sol should be kept between 0-40℃